Homeowner here who does not want to use Quats after reading this thread so I have a question about using bleach.
The question is whether there is a point where bleach sprayed on concrete has decomposed sufficiently so as not to be an environmental issue. Can I spray on bleach with a mister (i.e. no run-off), let it sit for 24 hours and rinse the next day and have confidence that the bleach has decomposed to a non-toxic substance? ChatGPT has some informative information and since I’m using it outside I’m not concerned about gas release. But I can’t quite determine is the other decomposition elements are harmful or not. If CaCO3Girl, our resident chemist can chime in on the topic it would be helpful to have such information, and to have discussions with others on why not to use Quats. Thanks.
Chat says…
"Sodium hypochlorite (NaOCl), the active ingredient in household bleach, does not decompose into completely harmless elements. When sodium hypochlorite breaks down, it typically forms various byproducts, including salt (sodium chloride, NaCl) and oxygen gas (O2), along with other compounds depending on the specific conditions.
The decomposition of sodium hypochlorite can be accelerated by factors such as exposure to light, heat, pH changes, and the presence of certain contaminants. For example, when bleach is exposed to sunlight or heat, it can undergo a reaction known as photodecomposition, where it decomposes into salt, water, and oxygen gas:
[ 2 \text{ NaOCl} \rightarrow 2 \text{ NaCl} + \text{O}_2 + \text{H}_2\text{O} ]
While the byproducts of sodium hypochlorite decomposition, such as salt and water, are generally less harmful than the original compound, it’s important to note that bleach itself and some of its decomposition byproducts can still pose risks to human health and the environment if not handled properly. Additionally, certain reactions involving sodium hypochlorite can produce chlorine gas (Cl2), a toxic and corrosive substance.
Therefore, it’s essential to follow safety guidelines and use bleach and other chlorine-based products with caution, ensuring proper ventilation and avoiding mixing them with other household chemicals to prevent the formation of potentially harmful compounds. Disposing of bleach properly and avoiding excessive use can also help minimize its environmental impact.”